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Publication: Computational study of the thermal rearrangement of acetoxy(methoxy)carbene.

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Title Computational study of the thermal rearrangement of acetoxy(methoxy)carbene.
Authors/Editors* Wojciech Czardybon, John Warkentin, Nick Henry Werstiuk
Where published* J.Phys.Org. Chem.
How published* Journal
Year* 2005
Volume 18
Number 6
Pages 486 – 490
Publisher
Keywords acetoxy(methoxy)carbene • carbene • concerted • computation • rearrangement
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Abstract
Thermolysis of 2-acetoxy-2-methoxy-5,5-dimethyl-3-1,3,4-oxadiazoline affords acetoxy(methoxy)carbene. Thermal rearrangement of acetoxy(methoxy)carbene to methyl pyruvate is a concerted 1,2-migration, avoiding a potential radical-pair mechanism.
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