Publication: Eta3-Vinylborane Complexes of Platinum and Nickel: Borataallyl- and Alkyl/Borataalkene-Like Coordination Modes
All || By Area || By Year| Title | Eta3-Vinylborane Complexes of Platinum and Nickel: Borataallyl- and Alkyl/Borataalkene-Like Coordination Modes | Authors/Editors* | K. B. Kolpin, D. J. H. Emslie |
|---|---|
| Where published* | Angewandte Chemie |
| How published* | Journal |
| Year* | 2010 |
| Volume | 49 |
| Number | |
| Pages | 2716-2719 |
| Publisher | |
| Keywords | |
| Link | http://onlinelibrary.wiley.com/doi/10.1002/anie.200906931/abstract |
| Abstract |
The vinylborane PhHCCHB(C6F5)2 reacts with zero-valent Groupâ 10 transition-metal precursors to form eta3-vinylborane complexes. The platinum tri-tert-butylphosphine complex exhibits an η3-borataallyl-like coordination mode whereas the nickel bis(triphenylphosphine) complex tends towards alkyl/borataalkene coordination. |
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